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- W2950135331 abstract "Abstract The TiCl4-NR3 reagent system is useful for carbon-carbon bond forming reactions such as the aldol and related condensation reactions, the diastereoselective coupling of phenyl acetic acid derivatives, the conversion of aryl alkyl ketimines and ketoximes to pyrroles, ketazines to dihydrodiazines, enamines to aromatic amines, N,N-dialkylanilines to the corresponding benzidine derivatives, trialkylamines to unsaturated aldehydes, diarylcyclobutanones, diarylcyclobutylamine derivatives via iminium ion intermediates and for the reductive coupling of aromatic aldehydes, aldimines and intramolecular reductive coupling of chiral diimine derivatives. In all cases, the organic products are obtained in moderate to good yields, in singlepot operations under ambient reaction conditions. Hence, these synthetic methods have considerable synthetic potential." @default.
- W2950135331 created "2019-06-27" @default.
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- W2950135331 date "2002-09-12" @default.
- W2950135331 modified "2023-10-01" @default.
- W2950135331 title "New synthetic methods using the TiCl4-NR3 reagent system" @default.
- W2950135331 doi "https://doi.org/10.3998/ark.5550190.0003.717" @default.
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