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• W2950143077 abstract "A new approach to the synthesis of medium-ring-sized trans-alkenolides, based on the oxidative fragmentation of a three-carbon ring in hydroxyalkyl substituted bicyclo[n.1.0]alkan-1-ols readily available from 2-alkylidenecycloalkanones, is described. This methodology was applied to the six-step transformation of cyclooctanone to the natural 12-membered trans-alkenolide antibiotic (+)-recifeiolide." @default.
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• W2950143077 date "2014-05-01" @default.
• W2950143077 modified "2023-09-23" @default.
• W2950143077 title "A highly stereoselective route to medium-ring-sized trans-alkenolides via oxidative fragmentation of bicyclic oxycyclopropane precursors: application to the synthesis of (+)-recifeiolide" @default.
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• W2950143077 doi "https://doi.org/10.1016/j.tet.2014.03.032" @default.
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