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- W2950147185 abstract "Irradiation of a methanolic solution of 3-methoxycyclohexenone and ethoxyethylene with 254 nm light gave four stereoisomeric head-to-tail [2+2] cycloadducts in the ratios indicated in Fig. 3. The structure and stereochemistry of all the isomers were determined by chemical correlations and spectroscopic means, respectively. The time-course product analysis suggested that, in this reaction, the exo and endo oriented π-complexes are equally formed, and both give the cycloadducts with a slight preference for antara-selectivity. The analogous cycloadduct of 3-aminocyclohexenone to ethoxyethylene decomposed into 2-ethoxycyclooctane-1, 5-dione on silica gel chromatography." @default.
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- W2950147185 date "1987-03-03" @default.
- W2950147185 modified "2023-09-27" @default.
- W2950147185 title "ChemInform Abstract: Photo-Cycloaddition of 3-Methoxycyclohexenone and 3-Aminocyclohexenone to Ethoxyethylene: Stereochemistry of the Cycloadducts." @default.
- W2950147185 cites W1506007494 @default.
- W2950147185 doi "https://doi.org/10.1002/chin.198709089" @default.
- W2950147185 hasPublicationYear "1987" @default.
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