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- W2950167413 abstract "Abstract Cyclic voltammetry between 900 and - 500 mV vs. SCE at a glassy carbon electrode in a solution containing 1 mM OsO4, 2 mM K4Ru(CN)6, and 0.5 M NaCl at pH 2.0 results in the accumulation of an electroactive film. After 20 cycles at 50 mV s−1 the deposit corresponds to 400 μC cm−2. The film is stable for several days, whether stored at open circuit in a supporting electrolyte or in air. The modified electrode catalyzes the oxidation of As(III); the anodic peak current at about 1.0 V vs. SCE is proportional to concentration. The mediation of the reduction of IrCl2−6 was studied at a modified rotating disk electrode. The charge propagation was rapid, so the reduction was limited by a combination of the cross-reaction rate and the permeation of the substrate into the film. The same behavior was observed when the electrode was prepared from a solution containing Fe(CN)4-6 rather than Ru(CN)4-6." @default.
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- W2950167413 date "1987-12-15" @default.
- W2950167413 modified "2023-09-23" @default.
- W2950167413 title "ChemInform Abstract: Characteristics of a Glassy Carbon Electrode Modified in a Mixture of Osmium Tetroxide and Hexacyanoruthenate." @default.
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- W2950167413 doi "https://doi.org/10.1002/chin.198750009" @default.
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