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- W2950174785 abstract "Highly selective synthesis of 1‐substituted ( E )‐buta‐1,3‐dienes via palladium‐catalyzed Suzuki–Miyaura cross‐coupling of ( E )‐alkenyl iodides with 4,4,5,5‐tetramethyl‐2‐vinyl‐1,3,2‐dioxaborolane ( 1 ) is reported. The vinylboronate pinacol ester ( 1 ) acts as a vinyl building block to show high chemoselectivity for the Suzuki–Miyaura pathway versus Heck coupling in the presence of biphasic conditions (Pd(PPh 3 ) 4 , aqueous K 2 CO 3 , toluene and ethanol). Copyright © 2014 John Wiley & Sons, Ltd." @default.
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- W2950174785 date "2014-01-29" @default.
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- W2950174785 title "A highly selective synthesis of 1-substituted (<i>E</i>)-buta-1,3-dienes with 4,4,5,5-tetramethyl-2-vinyl-1,3,2-dioxaborolane as building block" @default.
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- W2950174785 doi "https://doi.org/10.1002/aoc.3095" @default.
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