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• W2950175431 abstract "An efficient and concise synthetic route for biologically interesting polycycles bearing citran and chalcone nuclei was developed starting from a variety of trihydroxybenzenes with substituents on the ring. The key strategies involved an ethylenediamine diacetate-catalyzed cyclization by a domino aldol-type/electrocyclization/H-shift/hetero Diels–Alder reaction of trihydroxybenzenes and citral or trans,trans-farnesal. This methodology was applied successfully to the synthesis of three natural products, desbenzylidenerubramin, rubraine, sumadain A, and their unnatural derivatives." @default.
• W2950175431 created "2019-06-27" @default.
• W2950175431 creator A5065172118 @default.
• W2950175431 creator A5070142225 @default.
• W2950175431 date "2009-12-01" @default.
• W2950175431 modified "2023-09-26" @default.
• W2950175431 title "EDDA-catalyzed rapid synthetic routes for biologically interesting polycycles bearing citrans and chalcones: the first total synthesis of sumadain A" @default.
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• W2950175431 doi "https://doi.org/10.1016/j.tet.2009.10.045" @default.
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