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- W2950176985 abstract "It has been established that a cationic Rh(I)/(S)-Segphos or (S)-DTBM-Segphos complex and benzoic acid catalyze the enantioselective cycloisomerization of 1,6-enynes, possessing carbonyl groups at the enyne linkage, to 2-alkylidenebicyclo[3.1.0]hexanes. The present cycloisomerization may involve site selective γ-hydrogen elimination. The one-pot enantioselective cycloisomerization and lactonization of 1,6-enynes, leading to bicyclic lactones, has also been accomplished." @default.
- W2950176985 created "2019-06-27" @default.
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- W2950176985 date "2014-11-20" @default.
- W2950176985 modified "2023-09-27" @default.
- W2950176985 title "ChemInform Abstract: Enantioselective Cycloisomerization of 1,6-Enynes to Bicyclo[3.1.0]hexanes Catalyzed by Rhodium and Benzoic Acid." @default.
- W2950176985 cites W2315799004 @default.
- W2950176985 doi "https://doi.org/10.1002/chin.201449100" @default.
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