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- W2950185969 abstract "Alpha,beta-unsaturated ketones are no longer the missing dipolarophiles in catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides. In the presence of Cu(I)-Fesulphos complexes as catalysts (5 mol %), these substrates combine high reactivity, wide substitution tolerance, moderate to good endo/exo selectivities, and high enantiocontrol. The endo/exo-diastereoselectivity of the reaction is strongly dependent on the cis or trans nature of the enone moiety." @default.
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- W2950185969 date "2009-06-16" @default.
- W2950185969 modified "2023-10-17" @default.
- W2950185969 title "ChemInform Abstract: Catalytic Asymmetric 1,3-Dipolar Cycloaddition of Azomethine Ylides with α,β-Unsaturated Ketones." @default.
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- W2950185969 doi "https://doi.org/10.1002/chin.200924101" @default.
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