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- W2950186397 abstract "Diastereomerically pure cationic Rh(I) complexes derived from phosphinite thioglycosides I were used as catalysts in highly enantioselective hydrogenations of enamides. The conformational similarity of α-d-arabinopyranose with β-l-galactopyranose allows the synthesis of both enantiomers of α-amino acid derivatives such as d- and l-DOPA in excellent ee (97% and 98%), using derivatives of the former sugar as catalyst precursors." @default.
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- W2950186397 date "2009-01-06" @default.
- W2950186397 modified "2023-10-18" @default.
- W2950186397 title "ChemInform Abstract: Asymmetric Enamide Hydrogenation Using Phosphinite Thioglycosides: Synthesis of D- and L-Aminoesters Using D-Sugars as Catalyst Precursors." @default.
- W2950186397 cites W2085812129 @default.
- W2950186397 doi "https://doi.org/10.1002/chin.200901080" @default.
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