Matches in SemOpenAlex for { <https://semopenalex.org/work/W2950193826> ?p ?o ?g. }
Showing items 1 to 69 of
69
with 100 items per page.
- W2950193826 abstract "Abstract Various α -ketophosphonates, RC(0)P(0)(OR′)2, are catalytically decarbonylated to give phosphonates, RP(0)(OR′)2, on treatment with PdR2L2 (R[dbnd]Me, Et; L[dbnd]tertiary phosphine) or Pd(PPh3)4. The reaction of trans-PdEt2(PMe3)2 with RC(0)P(0)(OR′)2 for several minutes under toluene reflux conditions affords trans-Pd(PMe3)2{C(0)R}{P(0)(OR′)2} as yellow crystals. The isolated palladium complexes yield the corresponding phosphonate in toluene at reflux temperature and also serve as a catalyst for the decarbonylation of α-ketophosphonates. The overall catalytic decarbonylation reaction is discussed." @default.
- W2950193826 created "2019-06-27" @default.
- W2950193826 creator A5016097192 @default.
- W2950193826 creator A5037289392 @default.
- W2950193826 creator A5049165232 @default.
- W2950193826 creator A5075395680 @default.
- W2950193826 date "2010-08-20" @default.
- W2950193826 modified "2023-09-25" @default.
- W2950193826 title "ChemInform Abstract: Palladium Catalyzed Carbon-Phosphorus Bond Activation: Decarbonylation Reaction of α-Ketophosphonates" @default.
- W2950193826 cites W1981637913 @default.
- W2950193826 doi "https://doi.org/10.1002/chin.199336115" @default.
- W2950193826 hasPublicationYear "2010" @default.
- W2950193826 type Work @default.
- W2950193826 sameAs 2950193826 @default.
- W2950193826 citedByCount "0" @default.
- W2950193826 crossrefType "journal-article" @default.
- W2950193826 hasAuthorship W2950193826A5016097192 @default.
- W2950193826 hasAuthorship W2950193826A5037289392 @default.
- W2950193826 hasAuthorship W2950193826A5049165232 @default.
- W2950193826 hasAuthorship W2950193826A5075395680 @default.
- W2950193826 hasConcept C132190689 @default.
- W2950193826 hasConcept C134121241 @default.
- W2950193826 hasConcept C155647269 @default.
- W2950193826 hasConcept C161790260 @default.
- W2950193826 hasConcept C178790620 @default.
- W2950193826 hasConcept C185592680 @default.
- W2950193826 hasConcept C191897082 @default.
- W2950193826 hasConcept C192562407 @default.
- W2950193826 hasConcept C2777716191 @default.
- W2950193826 hasConcept C2778142098 @default.
- W2950193826 hasConcept C502130503 @default.
- W2950193826 hasConceptScore W2950193826C132190689 @default.
- W2950193826 hasConceptScore W2950193826C134121241 @default.
- W2950193826 hasConceptScore W2950193826C155647269 @default.
- W2950193826 hasConceptScore W2950193826C161790260 @default.
- W2950193826 hasConceptScore W2950193826C178790620 @default.
- W2950193826 hasConceptScore W2950193826C185592680 @default.
- W2950193826 hasConceptScore W2950193826C191897082 @default.
- W2950193826 hasConceptScore W2950193826C192562407 @default.
- W2950193826 hasConceptScore W2950193826C2777716191 @default.
- W2950193826 hasConceptScore W2950193826C2778142098 @default.
- W2950193826 hasConceptScore W2950193826C502130503 @default.
- W2950193826 hasLocation W29501938261 @default.
- W2950193826 hasOpenAccess W2950193826 @default.
- W2950193826 hasPrimaryLocation W29501938261 @default.
- W2950193826 hasRelatedWork W1967701938 @default.
- W2950193826 hasRelatedWork W1967854256 @default.
- W2950193826 hasRelatedWork W1970985570 @default.
- W2950193826 hasRelatedWork W1997179973 @default.
- W2950193826 hasRelatedWork W2007932671 @default.
- W2950193826 hasRelatedWork W2013550026 @default.
- W2950193826 hasRelatedWork W2014110335 @default.
- W2950193826 hasRelatedWork W2057255640 @default.
- W2950193826 hasRelatedWork W2096030135 @default.
- W2950193826 hasRelatedWork W2120434252 @default.
- W2950193826 hasRelatedWork W2139114214 @default.
- W2950193826 hasRelatedWork W2171361506 @default.
- W2950193826 hasRelatedWork W2912502021 @default.
- W2950193826 hasRelatedWork W2949769851 @default.
- W2950193826 hasRelatedWork W2950839370 @default.
- W2950193826 hasRelatedWork W2951876727 @default.
- W2950193826 hasRelatedWork W2952644792 @default.
- W2950193826 hasRelatedWork W2952783673 @default.
- W2950193826 hasRelatedWork W2952930596 @default.
- W2950193826 hasRelatedWork W2231086706 @default.
- W2950193826 isParatext "false" @default.
- W2950193826 isRetracted "false" @default.
- W2950193826 magId "2950193826" @default.
- W2950193826 workType "article" @default.