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- W2950196047 abstract "The nickel nitrosyl cations [Ni(NO)Ln]+(L = PPh3, n= 2 or 3; L = PMePh2, n= 3) have been prepared from the reaction of [Ni(CO)2L2] with NOPF6 in C6H6–MeOH or from the reaction of [NiCl2L2] with Na[NO2] and L in the presence of CO. Some reactions of [Ni(NO)(PPh3)3]+ with the nucleophiles [OMe]–, X–(X = Cl, Br, or I), [S2CNR2]–, Ph2P[CH2]2PPh2, and PMePh2, have been examined. A 31P n.m.r. study reveals that the complex [Ni(NO)(PPh3)3][PF6] probably exists in two isomeric forms, one of symmetry C3v and the other of C2v." @default.
- W2950196047 created "2019-06-27" @default.
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- W2950196047 date "1977-06-07" @default.
- W2950196047 modified "2023-09-26" @default.
- W2950196047 title "ChemInform Abstract: TRANSITION-METAL NITROSYL COMPOUNDS. PART 12. BIS- AND TRIS-(TERTIARY PHOSPHINE)NITROSYLNICKEL(II) HEXAFLUOROPHOSPHATE COMPLEXES" @default.
- W2950196047 cites W2089104925 @default.
- W2950196047 doi "https://doi.org/10.1002/chin.197723323" @default.
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