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- W2950200772 abstract "Tomentosenol A (1), along with a pair of epimers, 4S-focifolidione (2) and 4R-focifolidione (3), were isolated from the leaves of Rhodomyrtus tomentosa. 1 was the first example of a new meroterpenoid class with a unique skeleton that contained a free syncarpic acid coupled with a terpenoid unit, and showed excellent antimicrobial and cytotoxic activities. The absolute configuration of 1 was unambiguously determined by a chemical conversion between 1 and the predetermined 2. In contrast to the common hetero Diels–Alder cycloaddition embodied in previously reported meroterpenoid biosynthesis, an Alder-ene reaction was proposed as the key transformation to account for the biosynthesis of 1, which was confirmed by a biomimetic total synthesis." @default.
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- W2950200772 date "2016-07-01" @default.
- W2950200772 modified "2023-09-26" @default.
- W2950200772 title "ChemInform Abstract: Isolation, Synthesis, and Biological Activity of Tomentosenol A from the Leaves of Rhodomyrtus tomentosa." @default.
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- W2950200772 doi "https://doi.org/10.1002/chin.201631214" @default.
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