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- W2950207842 abstract "α-Arylation of various ketones with aryl chlorides and bromides using the well-defined and air-stable (DtBPF)PdX2 (X = Cl, Br) catalysts gave 80−100% yield of the coupled products under relatively mild conditions at low catalyst loadings. The X-ray structure of (DtBPF)PdCl2 revealed the largest P−Pd−P bite angle (104.2°) for a ferrocenyl bisphosphine ligand. 31P NMR monitoring of (DtBPF)PdCl2-catalyzed reaction of 4-chlorotoluene with propiophenone indicated that DtBPF remained coordinated in a bidentate mode during the catalytic cycle." @default.
- W2950207842 created "2019-06-27" @default.
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- W2950207842 date "2008-05-20" @default.
- W2950207842 modified "2023-09-24" @default.
- W2950207842 title "ChemInform Abstract: α-Arylation of Ketones Using Highly Active, Air-Stable (DtBPF)PdX2(X: Cl, Br) Catalysts." @default.
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- W2950207842 doi "https://doi.org/10.1002/chin.200821094" @default.
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