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- W2950207845 abstract "The articulation of the notion of “frustrated Lewis pairs” (FLPs), which emerged from the discovery that H2 can be reversibly activated by combinations of sterically encumbered Lewis acids and bases, has prompted a great deal of recent activity. Perhaps the most remarkable consequence has been the development of FLP catalysts for the hydrogenation of a range of organic substrates. In the past 9 years, the substrate scope has evolved from bulky polar species to include a wide range of unsaturated organic molecules. In addition, effective stereoselective metal-free hydrogenation catalysts have begun to emerge. The mechanism of this activation of H2 has been explored, and the nature and range of Lewis acid/base combinations capable of effecting such activation have also expanded to include a variety of non-metal species. The reactivity of FLPs with a variety of other small molecules, including olefins, alkynes, and a range of element oxides, has also been developed. Although much of this latter chemistry has..." @default.
- W2950207845 created "2019-06-27" @default.
- W2950207845 creator A5037978366 @default.
- W2950207845 date "2015-10-27" @default.
- W2950207845 modified "2023-09-25" @default.
- W2950207845 title "ChemInform Abstract: Frustrated Lewis Pairs" @default.
- W2950207845 cites W2142839187 @default.
- W2950207845 doi "https://doi.org/10.1002/chin.201546248" @default.
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