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• W2950209398 abstract "Hydrocarbon tribopolymer, a type of polymer formed due to friction between surfaces, is a major impediment to the development of micro- and nanoelectromechanical systems (MEMS/NEMS) devices for industrial application. Tribopolymer buildup can prevent MEMS and NEMS from making or breaking electrical contact. We describe the adsorption of benzene (C6H6) on the RuO2(110) surface using density functional theory. This adsorption is an important initial step in the mechanism of hydrocarbon tribopolymer layer formation on MEMS and NEMS devices. The adsorption interaction is studied by considering three oxygen coverages of RuO2(110) and all the possible adsorption sites for benzene. We find that adsorption of benzene on O-poor RuO2(110) via C-Ru bonds is stronger than adsorption on the O-rich RuO2(110) via H-O bonds. For an in-depth study of the adsorption behavior, we include the van der Waals interaction for a holistic investigation. By incorporating the thermodynamic chemical potentials into the adsorption simulations, we describe a model that can provide guidance for realistic situations." @default.
• W2950209398 created "2019-06-27" @default.
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• W2950209398 date "2016-12-09" @default.
• W2950209398 modified "2023-09-27" @default.
• W2950209398 title "Adsorption of Benzene on the RuO2(110) Surface" @default.
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• W2950209398 hasPublicationYear "2016" @default.
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