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- W2950216095 abstract "The first copper-catalyzed asymmetric decarboxylative [4 + 1] cycloaddition of propargylic carbamates and sulfur ylides was successfully developed. This strategy led to a series of chiral indolines with synthetically flexible alkyne groups in good yields and with high enantio- and diastereoselectivities (up to 99% yield, 98% ee, and >95:5 dr). A possible mechanism and stereoinduction mode with copper-allenylidenes were proposed as the possible dipolar intermediate." @default.
- W2950216095 created "2019-06-27" @default.
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- W2950216095 date "2016-12-01" @default.
- W2950216095 modified "2023-09-27" @default.
- W2950216095 title "ChemInform Abstract: Catalytic Asymmetric [4 + 1] Annulation of Sulfur Ylides with Copper-Allenylidene Intermediates." @default.
- W2950216095 cites W2465642392 @default.
- W2950216095 doi "https://doi.org/10.1002/chin.201651130" @default.
- W2950216095 hasPublicationYear "2016" @default.
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