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- W2950219036 abstract "The stereoselective synthesis of (Z)-dienediynes 2 related to the neocarzinostatin chromophore 1 is described. (Z)-Bis(enol triflate) 3, accessible stereoselectively from 2-formylcyclopentanone in 2 steps, serves as the key intermediate. It is subjected to consecutive Pd(0)-catalyzed couplings with two different alkynes and furnishes 2 via monocoupling products 8." @default.
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- W2950219036 date "1992-01-01" @default.
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- W2950219036 title "Regiocontrol in Pd(0)‐Mediated Couplings of a Bis(enol triflate) with Alkynes — Stereoselective Syntheses of Monocyclic Dienediynes Related to the Neocarzinostatin Chromophore" @default.
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- W2950219036 doi "https://doi.org/10.1002/cber.19921250143" @default.
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