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- W2950221888 abstract "A reinvestigation of the Claisen rearrangement of 2,5-bis(allyloxy)tropone led to the isolation of three diallyl-5-hydroxytropolones along with an intermediary thermolysate, 3-allyl-5-allyloxytropolone. The structure of the formerly identified product was revised from 3,6-diallyl-5-hydroxytropolone to 4,6-diallyl-5-hydroxytropolone. The involvement of no cleavage-recombination process was established by cross-over deuterium labelling experiments. These derivatives were respectively converted to p-tropoquinones, one of which was further converted to a cyclohepta[b]pyranone derivative by an electrochemical reaction." @default.
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- W2950221888 date "1987-10-06" @default.
- W2950221888 modified "2023-09-25" @default.
- W2950221888 title "ChemInform Abstract: Thermal Rearrangement of 2,5-Bis(allyloxy)tropone, Revisited. Formation of Four Thermolysates Under the Claisen Rearrangement Conditions and Structure Revision of the Major Thermolysate." @default.
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- W2950221888 doi "https://doi.org/10.1002/chin.198740131" @default.
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