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• W2950233721 endingPage "4918" @default.
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• W2950233721 abstract "Asymmetric assembly of atropisomeric anilines from abundant and readily available precursors is one of the most challenging but valuable processes in organic synthesis. The use of highly efficient Smiles rearrangement to accomplish switchable enantioselective amination reactions of O-arenes provides access to nonsymmetric 2'-amino[1,1'-binaphthalen]-2-ol (i.e., NOBIN-type) and [1,1'-binaphthalene]-2,2'-diamine (i.e., BINAM-type) derivatives. This transition metal-free strategy provides a powerful way to access a wide range of advanced highly functionalized enantioenriched anilines." @default.
• W2950233721 created "2019-06-27" @default.
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• W2950233721 creator A5054419328 @default.
• W2950233721 date "2019-06-11" @default.
• W2950233721 modified "2023-09-24" @default.
• W2950233721 title "Switchable Smiles Rearrangement for Enantioselective <i>O</i>-Aryl Amination" @default.
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• W2950233721 doi "https://doi.org/10.1021/acs.orglett.9b01848" @default.
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