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- W2950236883 abstract "The design of efficient and general methods for the selective oxyfunctionalization of unactivated carbon−hydrogen bonds continues to represent a major challenge for the community of chemists, despite the fact that the oxidation of alkanes is a major feature of the chemical economy. A low level of selectivity is characteristic of large-scale oxidation of hydrocarbons performed under customary industrial oxidizing conditions (e.g., the catalytic air oxidation of cycloalkanes); in these processes, selectivity is difficult to control, because they are often impacted by the usual problems associated with free-radical chain reactions. Thus, in the last decades much work has been devoted to the search for general methods of selective oxidation that could be applied to a variety of satured hydrocarbons. In this context, just a few leading methods appear encouraging at the present time. This Account addresses a new approach developed in our laboratory, consisting in the application of isolated dioxiranes, a class ..." @default.
- W2950236883 created "2019-06-27" @default.
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- W2950236883 date "2006-05-16" @default.
- W2950236883 modified "2023-09-25" @default.
- W2950236883 title "A Novel Approach to the Efficient Oxygenation of Hydrocarbons under Mild Conditions. Superior Oxo Transfer Selectivity Using Dioxiranes" @default.
- W2950236883 cites W2112758391 @default.
- W2950236883 doi "https://doi.org/10.1002/chin.200620247" @default.
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