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- W2950238232 abstract "Abstract The enzymatic reduction of hydrophobic ketones in cyclodextrin containing media is reported yielding the corresponding alcohols ( S )-1-(2-naphthyl)-ethanol, ( S )-( E )-4-phenyl-3-en-2-ol and 1,2,3,4-tetrahydro-2-(1-hydroxyethyl)-1-oxonaphthalene in good yield and high enantiomeric excess. The reaction was catalyzed by a carbonyl reductase from Candida parapsilosis , NADH regeneration was carried out using either 2-propanol in a substrate coupled mode or formate dehydrogenase from Candida boidinii and formate as hydrogen donor. In continuous experiments high stability of the enzymes in media containing heptakis-(2,6-di- O -methyl)-β-cyclodextrin could be demonstrated. Space time yields of 120 g/(Ld) were obtained under not yet optimized conditions during the production of ( S )-1-(2-naphthyl)-ethanol." @default.
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- W2950238232 date "2010-06-13" @default.
- W2950238232 modified "2023-09-25" @default.
- W2950238232 title "ChemInform Abstract: Asymmetric Reductions in Aqueous Media: Enzymatic Synthesis in Cyclodextrin Containing Buffers." @default.
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- W2950238232 doi "https://doi.org/10.1002/chin.199942096" @default.
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