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- W2950241718 abstract "New group 14 5-metallated pyrrole-2-carbaldehydes 5-R3E(C4H2NR′)CHO (E Si, Ge, Sn; R Me, Et, nBu; R′ H, Me) have been regiospecifically prepared from corresponding pyrrole-2-carbaldehydes by either (i) 5-lithiation after protection of the aldehyde function by treatment with lithium N-methylpiperazide or by formation of an azafulvene dimer or (ii) metallation by R3EX (X Cl, Br). The 5-silylated compound (E Si, R R′ Me) has been also obtained from 1-methyl-2,5-bis(trimethylsilyl)pyrrole." @default.
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- W2950241718 date "1992-01-01" @default.
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- W2950241718 title "Pyrrolyl compounds of main group elements. Synthesis of group 14 5-metallated pyrrole-2-carbaldehydes" @default.
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- W2950241718 doi "https://doi.org/10.1016/0022-328x(92)83112-u" @default.
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