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- W2950243349 abstract "A new methodology for the asymmetric synthesis of β-hydroxy acid was developed. Dirhodium(II)-catalyzed C–H insertion of α-alkoxydiazoketone (3), which was prepared from primary alkyl halide (1) and readily available chiral α-hydroxy acid (2), gave stereoselectively 2,5-cis-disubstituted 3(2H)-furanone (4). The Baeyer-Villiger reaction of 4 followed by treatment with an acid afforded chiral β-hydroxy acid (6) with high optical purity." @default.
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- W2950243349 date "2003-08-26" @default.
- W2950243349 modified "2023-10-17" @default.
- W2950243349 title "Asymmetric Synthesis of β-Hydroxy Acid via Stereoselective Dirhodium(II)-Catalyzed C—H Insertion of α-Alkoxydiazoketone." @default.
- W2950243349 cites W2139247752 @default.
- W2950243349 doi "https://doi.org/10.1002/chin.200334070" @default.
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