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- W2950243606 abstract "A β-diketiminato magnesium alkyl complex, [CH{C(Me)NDipp}2 }MgnBu] (Dipp=2,6-iPr2 C6 H3 ), was shown to be an effective pre-catalyst for the first reported catalytic hydroboration of alkyl- and aryl-substituted carbodiimides with pinacol borane (HBpin). The catalytic reactions proceed under mild conditions to afford the corresponding N-borylated formamidine compounds in good yields. The reactions were observed to proceed through the intermediacy of magnesium amidinate and formamidinatoborate intermediates and an example of one of these latter species has been structurally characterised by an X-ray diffraction analysis. Crucially, no formation of the N-boryl formamidine products was observed in the absence of additional equivalents of the carbodiimide and HBpin substrates. This observation, supported by the evolution of a sigmoidal kinetic profile for the hydroboration of dicyclohexylcarbodiimide, has been rationalised as the consequence of an allosteric effect of the pinacol borane and carbodiimide on the magnesium formamidinatoborate intermediates." @default.
- W2950243606 created "2019-06-27" @default.
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- W2950243606 date "2016-09-01" @default.
- W2950243606 modified "2023-09-27" @default.
- W2950243606 title "ChemInform Abstract: Magnesium Catalysis for the Hydroboration of Carbodiimides." @default.
- W2950243606 cites W2338457389 @default.
- W2950243606 doi "https://doi.org/10.1002/chin.201640087" @default.
- W2950243606 hasPublicationYear "2016" @default.
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