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- W2950245840 endingPage "443" @default.
- W2950245840 startingPage "389" @default.
- W2950245840 abstract "Abstract A unique feature of molecular iodine by far, is its ability to bind to polymeric materials. A plethora of natural and synthetic polymers develop complexes when treated with molecular iodine, or with a mixture of molecular iodine and potassium iodide. Many unexpected findings have been encountered upon complexation of iodine and the polymer skeleton, including the color formation, the polymer morphology changes, the complexation sites or regions, the biological activity, and the electrical conductivity enhancement of the complexes, with polyiodides (I n ¯), mainly I 3 ¯ and I 5 ¯, as the actual binding species. Natural polymers that afford such complexes with iodine species are starch (amylose and amylopectin), chitosan, glycogen, silk, wool, albumin, cellulose, xylan, and natural rubber; iodine-starch being the oldest iodine-natural polymer complex. By contrast, numerous synthetic polymers are prone to make complexes, including poly(vinyl alcohol) (PVA), poly(vinyl pyrrolidone) (PVP), nylons, poly(Schiff base)s, polyaniline, unsaturated polyhydrocarbons (carbon nanotubes, fullerenes C 60 /C 70 , polyacetylene; iodine-PVA being the oldest iodine-synthetic polymer complex." @default.
- W2950245840 created "2019-06-27" @default.
- W2950245840 creator A5025089415 @default.
- W2950245840 date "2013-08-01" @default.
- W2950245840 modified "2023-10-13" @default.
- W2950245840 title "Molecular iodine/polymer complexes" @default.
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