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• W2950247612 endingPage "2950" @default.
• W2950247612 startingPage "2938" @default.
• W2950247612 abstract "The palladium-catalyzed monoamination of symmetric dibromobenzenes can be performed using a catalyst based on Pd2dba3 and BINAP in the presence of NaO(t-Bu). The analogous transformation of non-symmetric bromoiodobenzenes is most effectively performed with Xantphos as the ligand, while reactions with BINAP were non-selective. These transformations can be scaled uneventfully to >10 g quantities. They do not require drybox or Schlenk techniques, and all reagents are weighed out in air. The resulting monobromoanilines are versatile intermediates for further synthetic transformations." @default.
• W2950247612 created "2019-06-27" @default.
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• W2950247612 creator A5091492982 @default.
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• W2950247612 date "2008-03-01" @default.
• W2950247612 modified "2023-10-06" @default.
• W2950247612 title "Palladium-catalyzed monoamination of dihalogenated benzenes" @default.
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• W2950247612 doi "https://doi.org/10.1016/j.tet.2008.01.070" @default.
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