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- W2950255057 abstract "A highly efficient and enantioselective synthesis of γ-lactams and γ-amino acids by Rh-catalyzed asymmetric hydrogenation has been developed. Using the Rh-(S,S)-f-spiroPhos complex, under mild conditions a wide range of 3-cyano acrylate esters including both E and Z-isomers and β-cyano-α-aryl-α,β-unsaturated ketones were first hydrogenated with excellent enantioselectivities (up to 98% ee) and high turnover numbers (TON up to 10000)." @default.
- W2950255057 created "2019-06-27" @default.
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- W2950255057 date "2016-05-01" @default.
- W2950255057 modified "2023-09-23" @default.
- W2950255057 title "ChemInform Abstract: Highly Efficient Asymmetric Hydrogenation of Cyano-Substituted Acrylate Esters for Synthesis of Chiral γ-Lactams and Amino Acids." @default.
- W2950255057 cites W2193021237 @default.
- W2950255057 doi "https://doi.org/10.1002/chin.201623047" @default.
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