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- W2950255588 abstract "The asymmetric nitro-Mannich reactions of nitroalkanes and in situ generated N-Boc-imines were achieved with a new type of thiourea-guanidine bifunctional organocatalyst. The novel transformations exhibited good diastereoselectivities, and the adducts bearing adjacent chiral centers were generally obtained in moderate to high enantioselectivities (up to 94% ee). This reaction provides a concise and alternative route converting readily accessible and stable N-carbamate amido sulfones into optically active 1,2-diamino compounds." @default.
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- W2950255588 date "2011-11-11" @default.
- W2950255588 modified "2023-09-25" @default.
- W2950255588 title "Enantio- and Diastereoselective Nitro-Mannich Reactions with in situ Generated N-Boc-imines Catalyzed by a Bifunctional Thiourea-Guanidine Catalyst" @default.
- W2950255588 doi "https://doi.org/10.1055/s-0031-1289885" @default.
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