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- W2950263695 abstract "A catalytic hypervalent iodine oxidation of p-alkoxyphenols using 4-iodophenoxyacetic acid (1a) and Oxone® was developed. Reaction of p-alkoxyphenol (2) with a catalytic amount of 1a in the presence of Oxone® as a co-oxidant in 2,2,2-trifluoroethanol–water (1 : 2) gave the corresponding p-quinone (3) in excellent yield without special operation. The substituent effect on iodobenzene ring in the oxidation was observed; p-alkoxy is the most effective, with the series following the approximate order p-RO>p-Me, o-MeO, m-MeO>H>o-CO2H. And remarkable solvent effects were observed." @default.
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- W2950263695 date "2009-09-01" @default.
- W2950263695 modified "2023-09-27" @default.
- W2950263695 title "ChemInform Abstract: Catalytic Hypervalent Iodine Oxidation Using 4-Iodophenoxyacetic Acid and Oxone®: Oxidation of p-Alkoxyphenols to p-Benzoquinones." @default.
- W2950263695 cites W2082129324 @default.
- W2950263695 doi "https://doi.org/10.1002/chin.200935083" @default.
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