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- W2950270897 abstract "A highly regio- and enantioselective asymmetric vinylogous Mannich reaction of readily available fluorinated aldimines bearing a chiral auxiliary [(S)-1-phenylethyl group] with siloxyfurans to afford chiral fluorine-containing γ-butenolide or γ-lactone derivatives has been developed in the presence of silver acetate (10 mol%) and axially chiral phosphine-oxazoline ligand L1 (11 mol%). In most cases, the corresponding fluorinated adducts were obtained in high yields, good to excellent enantiomeric excesses and up to > 20:1 dr." @default.
- W2950270897 created "2019-06-27" @default.
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- W2950270897 date "2011-07-07" @default.
- W2950270897 modified "2023-09-23" @default.
- W2950270897 title "ChemInform Abstract: Highly Diastereo- and Enantioselective Vinylogous Mannich Reactions of Fluorinated Aldimines with Siloxyfurans." @default.
- W2950270897 cites W2170795647 @default.
- W2950270897 doi "https://doi.org/10.1002/chin.201131101" @default.
- W2950270897 hasPublicationYear "2011" @default.
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