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- W2950272018 abstract "A facile and highly stereoselective retro-[1,4] Brook rearrangement of 3-silyl allyloxysilanes has been discovered. While basic hydrolysis of the formed (Z)-3,3-bissilyl lithium enolates provides 3,3-bissilyl carbonyl compounds efficiently, trapping the species with various electrophiles including alkyl halides leads to the exclusive O-substituted (Z)-3,3-bissilyl enol derivatives that can undergo a Sakurai reaction with aldehyde to produce the synthetically useful 1,2-diol diastereoselectively." @default.
- W2950272018 created "2019-06-27" @default.
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- W2950272018 date "2010-10-28" @default.
- W2950272018 modified "2023-10-07" @default.
- W2950272018 title "Efficient Approach to 3,3-Bissilyl Carbonyl and Enol Derivatives via Retro-[1,4] Brook Rearrangement of 3-Silyl Allyloxysilanes" @default.
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- W2950272018 doi "https://doi.org/10.1021/ol102352w" @default.
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