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- W2950276166 abstract "Abstract A number of chiral secondary amines have been prepared and used as precursors to the corresponding chiral lithium amide bases. Treatment of either cis -2,6-dimethylcyclohexanone or 4- tert -butylcyclohexanone with a chiral lithium amide, followed by electrophilic quench, gives chiral products in up to 88% enantiomeric excess. The results with 4- tert -butylcyclohexanone are in disagreement with an earlier literature report, giving products of lower enantiomeric excess but higher optical rotation." @default.
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- W2950276166 date "1990-05-01" @default.
- W2950276166 modified "2023-09-27" @default.
- W2950276166 title "ChemInform Abstract: Asymmetric Deprotonation of Prochiral Ketones Using Chiral Lithium Amide Bases." @default.
- W2950276166 cites W2008043918 @default.
- W2950276166 doi "https://doi.org/10.1002/chin.199018067" @default.
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