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- W2950279410 abstract "Abstract The syntheses, structure and ionic conductivity of Ag 12.4 Na 1.6 Mo 18 As 4 O 71 are reported. Crystals and polycrystalline powders are synthesized by solid state reaction. It crystallized in the monoclinic space group C 2/ c with a = 20.032 A, b = 16.872 A, c = 19.373 A and β = 112.14°. The structure can be described by the assemblage of Mo 8 As 2 O 34 ribbons interconnected through Mo 2 O 7 groups. Monovalent cations are located around these ribbons. The ionic conductivities have been measured, on pellets of polycrystalline powders, between 423 and 663 K in the frequency range 1–13000 Hz, using diagrams of complex impedance. Impedance analysis suggests the presence of a dependent electrical relaxation temperature process in the material. Activation energy was obtained from Arrhenius plots (log σT versus 1000/ T ) and found to be 0.6 eV. The activation energies obtained from impedance and loss spectra are close. It suggests that the ionic transport in the elaborated material is due to a hopping mechanism. The dependence in frequency of the ac conductivity is found to obey Jonsher's relation." @default.
- W2950279410 created "2019-06-27" @default.
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- W2950279410 date "2012-09-01" @default.
- W2950279410 modified "2023-10-17" @default.
- W2950279410 title "Synthesis, structure and ionic conductivity of the molybdenum arsenate: Ag12.4Na1.6Mo18As4O71" @default.
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- W2950279410 doi "https://doi.org/10.1016/j.solidstatesciences.2012.07.021" @default.
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