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- W2950282419 abstract "Abstract The mixed ligand complex Fe(phen)(bipy)(NCS) 2 exhibiting a thermally induced spin state transition between the low spin ( 1 A 1 ) and high spin ( 5 T 2 ) states, has been synthesized and characterized by different techniques. The nature of the spin stare transition has been studied by 57 Fe Mossbauer spectroscopy and differential scanning calorimetry techniques. At spin transition temperature T c ⋍179 K, the values of isomeric shift and quadrupole splitting for the low and high spin states are δ LS =0.41, δ HS =1.01, Δ Eq LS =0.36 and Δ Eq HS =2.9 mm s −1 , respectively. Although the spin state transition for this complex is of first order, the value of Δ H = 1 kJ/mol is significantly less than the values observed for single ligand complexes Fe(phen) 2 (NCS) 2 and Fe(bipy) 2 (NCS) 2 . The possible reason for this behaviour has been pointed out." @default.
- W2950282419 created "2019-06-27" @default.
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- W2950282419 date "1988-03-08" @default.
- W2950282419 modified "2023-09-25" @default.
- W2950282419 title "ChemInform Abstract: Spin State Transition in Fe(1,10-phen)(2,2′-bipy)(NCS)2." @default.
- W2950282419 cites W2063166801 @default.
- W2950282419 doi "https://doi.org/10.1002/chin.198810328" @default.
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