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- W2950284186 abstract "Oxidation of the N-aminoquinazolones (10) and (11) generates the corresponding N-nitrenes which add intramolecularly to both double bonds. Although nitrene addition is stereospecifically cis, both faces of each double bond are attacked and consequently stereoisomers are formed. From the different selectivity of the N-nitrenes for the two double bonds in (10) and (11)[or (29)] by comparison with (15) and (24), respectively and from a consideration of the stereoisomer ratios, it is concluded that concerted addition of the N-nitrene to the double bonds in (10) and (11) obtains via a transition-state geometry resembling that shown in (34)." @default.
- W2950284186 created "2019-06-27" @default.
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- W2950284186 date "1987-09-01" @default.
- W2950284186 modified "2023-09-26" @default.
- W2950284186 title "ChemInform Abstract: Intramolecular Reactions of N-Nitrenes: Description of the Transition State Geometry for Addition to Alkenes." @default.
- W2950284186 cites W2157436311 @default.
- W2950284186 doi "https://doi.org/10.1002/chin.198735093" @default.
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