Matches in SemOpenAlex for { <https://semopenalex.org/work/W2950284857> ?p ?o ?g. }
Showing items 1 to 71 of
71
with 100 items per page.
- W2950284857 abstract "Publisher Summary This chapter discusses the reactions of organosulfur and organoselenium compounds mediated by transition metals. In organic synthetic reactions, the scope and applications of organosulfur and organoselenium chemistry have increased tremendously. Organosulfur complexes of low oxidation state metals are generally less stable than their phosphorus counterparts, but this relative instability lends the complexes their reactivity. Organosulfur ligands are the reactive centers of the complexes. Low-valent nickel species catalyze the reaction between Grignard reagents and aryl or alkenyl sulfide in the preparation of alkylarenes, biaryls, and alkenes. In contrast, ultra violet (UV) irradiation of dithiane or trithiane in the presence of [Fe(CO)5] leads to the scission of only one C–S bond and the formation of an asymmetric complex. The molybdenum dimer can be converted, by alkylation, to a cation, which can be transformed into an anion by two-electron chemical reduction. Although the thiolysis of alkoxycarbenes to form thiocarbenes is not a new reaction, the new method, in which a catalyst is used, minimizes the formation of unwanted side products and dramatically increases the yield." @default.
- W2950284857 created "2019-06-27" @default.
- W2950284857 creator A5032059711 @default.
- W2950284857 creator A5054215531 @default.
- W2950284857 date "2010-08-21" @default.
- W2950284857 modified "2023-09-27" @default.
- W2950284857 title "ChemInform Abstract: Formation and Reactions of Organosulfur and Organoselenium Organometallic Compounds" @default.
- W2950284857 cites W2111172309 @default.
- W2950284857 doi "https://doi.org/10.1002/chin.199302327" @default.
- W2950284857 hasPublicationYear "2010" @default.
- W2950284857 type Work @default.
- W2950284857 sameAs 2950284857 @default.
- W2950284857 citedByCount "0" @default.
- W2950284857 crossrefType "journal-article" @default.
- W2950284857 hasAuthorship W2950284857A5032059711 @default.
- W2950284857 hasAuthorship W2950284857A5054215531 @default.
- W2950284857 hasConcept C142724271 @default.
- W2950284857 hasConcept C161790260 @default.
- W2950284857 hasConcept C164361826 @default.
- W2950284857 hasConcept C178790620 @default.
- W2950284857 hasConcept C185592680 @default.
- W2950284857 hasConcept C204787440 @default.
- W2950284857 hasConcept C25366896 @default.
- W2950284857 hasConcept C2776910235 @default.
- W2950284857 hasConcept C2778775051 @default.
- W2950284857 hasConcept C2780263894 @default.
- W2950284857 hasConcept C2781076698 @default.
- W2950284857 hasConcept C40875361 @default.
- W2950284857 hasConcept C518881349 @default.
- W2950284857 hasConcept C71924100 @default.
- W2950284857 hasConceptScore W2950284857C142724271 @default.
- W2950284857 hasConceptScore W2950284857C161790260 @default.
- W2950284857 hasConceptScore W2950284857C164361826 @default.
- W2950284857 hasConceptScore W2950284857C178790620 @default.
- W2950284857 hasConceptScore W2950284857C185592680 @default.
- W2950284857 hasConceptScore W2950284857C204787440 @default.
- W2950284857 hasConceptScore W2950284857C25366896 @default.
- W2950284857 hasConceptScore W2950284857C2776910235 @default.
- W2950284857 hasConceptScore W2950284857C2778775051 @default.
- W2950284857 hasConceptScore W2950284857C2780263894 @default.
- W2950284857 hasConceptScore W2950284857C2781076698 @default.
- W2950284857 hasConceptScore W2950284857C40875361 @default.
- W2950284857 hasConceptScore W2950284857C518881349 @default.
- W2950284857 hasConceptScore W2950284857C71924100 @default.
- W2950284857 hasLocation W29502848571 @default.
- W2950284857 hasOpenAccess W2950284857 @default.
- W2950284857 hasPrimaryLocation W29502848571 @default.
- W2950284857 hasRelatedWork W1543582093 @default.
- W2950284857 hasRelatedWork W1981236981 @default.
- W2950284857 hasRelatedWork W1993173781 @default.
- W2950284857 hasRelatedWork W2012109659 @default.
- W2950284857 hasRelatedWork W2013866214 @default.
- W2950284857 hasRelatedWork W2088976690 @default.
- W2950284857 hasRelatedWork W2099270473 @default.
- W2950284857 hasRelatedWork W2136827921 @default.
- W2950284857 hasRelatedWork W2151455179 @default.
- W2950284857 hasRelatedWork W2160562986 @default.
- W2950284857 hasRelatedWork W2434805617 @default.
- W2950284857 hasRelatedWork W2473039054 @default.
- W2950284857 hasRelatedWork W2950296296 @default.
- W2950284857 hasRelatedWork W2951124985 @default.
- W2950284857 hasRelatedWork W2952680185 @default.
- W2950284857 hasRelatedWork W2953099080 @default.
- W2950284857 hasRelatedWork W2953776357 @default.
- W2950284857 hasRelatedWork W3047944935 @default.
- W2950284857 hasRelatedWork W3139544578 @default.
- W2950284857 hasRelatedWork W960232669 @default.
- W2950284857 isParatext "false" @default.
- W2950284857 isRetracted "false" @default.
- W2950284857 magId "2950284857" @default.
- W2950284857 workType "article" @default.