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- W2950299741 abstract "Binary Sb2O3-GeO2 glasses containing 45 mol% Sb2O3 and ternary Sb2O3-B2O3-GeO2 glasses containing 50 mol% GeO2 were prepared. Their densities (volumes), refractive indices, and infrared spectra were determined, and their colors and high-temperature viscosities were estimated visually. Small amounts of Sb2O3 (∼10 mol%) appear to perturb neither the Ge-O-Ge network nor those B-O-Ge networks with small B/Ge ratios (∼0.2). The B-O-Ge networks with larger B/Ge ratios (∼1.0) depolymerize in the presence of even less Sb2O3. Amounts of Sb2O3 >10 mol% appear to depolymerize the Ge-O-Ge and Ge-O-B networks progressively, possibly with the formation of chains. A structurally sensitive ir isofrequency contour technique developed for ternary glass systems was applied successfully to these Sb2O3-B2O3-GeO2 glasses. These contours can thus readily detect significant network depolymerization in the absence of the usual network modifiers." @default.
- W2950299741 created "2019-06-27" @default.
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- W2950299741 date "1973-08-28" @default.
- W2950299741 modified "2023-09-27" @default.
- W2950299741 title "ChemInform Abstract: DEPOLYMERIZATION OF GEO2 AND B2O3-GEO2 NETWORK GLASSES BY SB2O3" @default.
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- W2950299741 doi "https://doi.org/10.1002/chin.197335009" @default.
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