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- W2950301067 abstract "Abstract The enolization stereoselectivity of 3-pentanone by lithium tetramethylpiperidide mixed aggregates with butyllithium was studied and the results were compared to those obtained using lithium tetramethylpiperidide alone. The mixed aggregate resulted in a slightly higher stereoselectivity, and the selectivity increased with decreasing percent conversion of the lithium base. Ab initio and semiempirical PM3 calculations were performed to determine the activation enthalpies for the enolization reactions and the calculations were compared to the experimental results." @default.
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- W2950301067 date "2010-06-19" @default.
- W2950301067 modified "2023-09-26" @default.
- W2950301067 title "ChemInform Abstract: Mixed Aggregates of Lithium Tetramethylpiperidide with Butyllithium: Stereoselectivity of Ketone Enolization." @default.
- W2950301067 cites W2139789418 @default.
- W2950301067 doi "https://doi.org/10.1002/chin.199840029" @default.
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