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- W2950301422 abstract "2,4-Disubstituted 3-chlorofurans were synthesized in 42–69% overall yields by CuCl/bpy-catalyzed halogen atom transfer radical cyclization of 1-substituted 2,2,2-trichloroethyl allyl ethers to 2-substituted 3,3-dichloro-4-(1-chloroalkyl)tetrahydrofurans followed by base promoted dehydrochlorination. Diels–Alder reactions of 4-substituted 2-(2-furyl)-, 2-styryl-, and 2-crotyl-3-chlorofurans with dimethyl acetylenedicarboxylate occurred exclusively on the chlorofurano diene moieties and not on the non-chlorinated furano diene or the chlorinated exocyclic diene alternatives, demonstrating the predominance of the halogen effect in the furan Diels–Alder reaction." @default.
- W2950301422 created "2019-06-27" @default.
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- W2950301422 date "2008-01-01" @default.
- W2950301422 modified "2023-09-25" @default.
- W2950301422 title "Synthesis of 2,4-disubstituted 3-chlorofurans and the effect of the chlorine substituent in furan Diels–Alder reactions" @default.
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- W2950301422 doi "https://doi.org/10.1016/j.tetlet.2007.11.193" @default.
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