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• W2950302609 startingPage "3136" @default.
• W2950302609 abstract "The crystal structures of Sr2HoMn2O7 and Sr2YMn2O7 have been determined at 290 and 1.7 K from neutron and X-ray powder diffraction data. Both are distorted Ruddlesden−Popper structures formed by the intergrowth of rock-salt-like layers and perovskite-like blocks of tilted MnO6 octahedra (space group P42/mnm; for Ho at 290 K a = 5.40388(5), c = 19.9050(2) Å). The majority of the lanthanide cations are located in the rock-salt layers. Neither structure changes significantly on cooling to 1.7 K. There is evidence for neither charge ordering of Mn3+ and Mn4+ cations nor for long-range magnetic ordering. The magnetic susceptibility maximum observed previously is thus confirmed as signifying a transition to a spin-glass phase. The behavior of these compounds is contrasted with that of other Mn oxides which show long-range magnetic order and colossal magnetoresistance." @default.
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• W2950302609 date "1997-12-01" @default.
• W2950302609 modified "2023-10-16" @default.
• W2950302609 title "Neutron Diffraction Study of the Structural and Electronic Properties of Sr₂HoMn₂O₇ and Sr₂YMn₂O₇" @default.
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• W2950302609 doi "https://doi.org/10.1021/cm970431p" @default.
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