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- W2950305798 abstract "The tide compounds 4a-c have been prepared in a one-step procedure from 2,4-diamino-6-hydroxy-pyrimidine (1) and the corresponding arylidene substituted Meldrum's acids 2a-e in very good yields. Semiempirical theoretical calculations (AMI) reveal two favoured conformations (A and B) for compounds 4a-e. The 1H-nmr determinations, by using Karplus and Altona equations, clearly indicate that conformation A, with the aryl group on C5 in a pseudoaxial position, is that predominant in solution. The calculated charge density values for the olefinic carbons are in agreement with the experimental push-pull effect observed in the 13C-nmr spectra." @default.
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- W2950305798 date "1997-05-01" @default.
- W2950305798 modified "2023-09-27" @default.
- W2950305798 title "Synthesis and structural study of novel 5-aryl substituted 2-amino-4,7-dioxopyrido[2,3-d]pyrimidines" @default.
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- W2950305798 doi "https://doi.org/10.1002/jhet.5570340338" @default.
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