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- W2950308510 abstract "Infrared spectra of 5-methylcytosine in an argon matrix are reported. The results indicate that three tautomeric forms, amino-hydroxy, amino-oxo, and imino-oxo, exist simultaneously in the matrix. A UV-induced transformation of the amino-oxo form to the amino-hydroxy form was observed and utilized to separate the spectra of the tautomers. Ab initio quantum chemical calculations of the normal modes performed at the SCF/3-21G level of the theory for the three tautomers enable positive assignment of most of the observed bands" @default.
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- W2950308510 date "1990-12-11" @default.
- W2950308510 modified "2023-09-23" @default.
- W2950308510 title "ChemInform Abstract: Matrix Isolation and ab initio Theoretical Studies of the IR Spectrum of 5-Methylcytosine" @default.
- W2950308510 cites W2029272689 @default.
- W2950308510 doi "https://doi.org/10.1002/chin.199050032" @default.
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