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- W2950312672 abstract "Abstract Structural variations in acylsilane molecules allow a number of new selective synthetic processes to be performed which lead to sulfur-containing heterocycles, highly functionalized and unsaturated polycarbonyl derivatives, polyenes, and β - and γ -aminoalcohols. The synthesis of these compounds, most of them not easily accessible through conventional routes, takes advantage of the site-selective reactions occurring at the C–Si bonds, of the increased stability of acylsilanes with respect to that of the corresponding aldehydes and of the high diastereofacial selectivity introduced by the SiR 3 group. Herein we report the different synthetic strategies leading to the synthesis of several functionalized acylsilanes and their synthetic applications. The use of new selective polymetallic reagents for the nucleophilic silylation will be presented as well." @default.
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- W2950312672 date "1998-09-01" @default.
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- W2950312672 title "Newly designed acylsilanes as versatile tools in organic synthesis" @default.
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- W2950312672 doi "https://doi.org/10.1016/s0022-328x(98)00694-9" @default.
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