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- W2950316608 abstract "Abstract Glycolato peroxotitanates [Ti2(O2)2(glyc)2(H2O)4]·2H2O (1) and (NH4)6[Ti4(O2)4O2(glyc)4(Hglyc)2]·7H2O (2) (H2glyc = glycolic acid) have been isolated from the reactions of titanium tetra-n-butyl oxide with glycolic acid and hydrogen peroxide. Transformations of glycolato peroxotitanates depend on pH values of the solutions, that is pH = 1.0 for 1 and pH = 5.0 for 2 respectively. Decomposition of 1 results in the formation of the pure anatase-type TiO2 at 500 °C, while 2 results in the formation of the pure rutile-type TiO2 at 700 °C. The titanium atoms in 1 and 2 exist in pentagonal bipyramidal coordination environment. 1 is a dinuclear neutral complex containing two Ti(O2) (H2O)2 cores, which are linked by two deprotonated glycolate ligands. 2 comprises a tetranuclear titanium anion structure, which consists of two Ti2(O2)2 cores inter-linked through two bridged oxygen atoms. The XRD patterns and Raman spectra of TiO2 annealed from 1 and 2 at different temperature were explored." @default.
- W2950316608 created "2019-06-27" @default.
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- W2950316608 date "2019-09-01" @default.
- W2950316608 modified "2023-09-24" @default.
- W2950316608 title "Transformations of dimeric and tetrameric glycolato peroxotitanates and their thermal decompositions for the preparations of anatase and rutile oxides" @default.
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- W2950316608 doi "https://doi.org/10.1016/j.jssc.2019.06.008" @default.
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