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- W2950320607 abstract "A neutral ligand is synthesized and studied for the binding properties with anions by electrochemical methods. The binding of 1,8-bis[(N'-phenylureido)ethyloxy]anthraquinone (BPUA) with <TEX>$H_2PO_4^-$</TEX> makes cathodic shift of its electrochemical potentials and red shift of absorption band. This novel neutral anion receptor BPUA binds anions through hydrogen bonding and show high selectivity with <TEX>$H_2PO_4^-$</TEX> over <TEX>$CH_3CO_2^-,CI^-,{;}and{;}HSO_4^-$</TEX>. The selecivity of <TEX>H_2PO_4^-$</TEX> over <TEX>$CH_3CO_2^-,CI^-,{;}and{;}HSO_4^-$</TEX> may be attributed to the stronger hydrogen bonding with urea moiety and also with anthraquinone moiety of BPUA receptor, and also the higher complementarity of the cavity of BPUA for tetrahedral <TEX>H_2PO_4^-$</TEX>." @default.
- W2950320607 created "2019-06-27" @default.
- W2950320607 date "2003-10-20" @default.
- W2950320607 modified "2023-09-26" @default.
- W2950320607 title "Synthesis and Selective Recognition of Dihydrogen Phosphate by Urea-Anthraquinone" @default.
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- W2950320607 doi "https://doi.org/10.5012/bkcs.2003.24.10.1465" @default.
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