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- W2950331348 abstract "Abstract 3-Alkoxycycloalkenes undergo regio- and stereoselective halofluorination with pyridinium poly(hydrogen fluoride) and 1,3-dibromo-5,5-dimethylhydantoion or N -iodosuccinimide to give (1 S *,2 S *,3 S *)-1-alkoxy-3-fluoro-2-halocycloalkanes in good yields. Among the halofluorides, the 3-(2-propynyloxy) derivatives are in turn converted into bicyclic α-methylene-γ-butyrolactons containing a fluorine via radical cyclization followed by oxidation, leading to a stereospecific synthesis of (±)-4-fluoro-l- epi -damsin." @default.
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- W2950331348 date "1992-11-01" @default.
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- W2950331348 title "Regio- and stereo-controlled synthesis of bicyclic α-methylene-γ-butyrolactones containing a fluorine via halofluorination-radical cyclization" @default.
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- W2950331348 doi "https://doi.org/10.1016/s0040-4039(00)60917-6" @default.
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