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- W2950334589 abstract "New, chiral 1,3,2-oxazaphospholidine-borane complexes 3a-b and 8a-d were synthesized from the β-amino alcohols 1a-b and 6a-d. The borane complexes 3, 8a, 8c, and 8d were allowed to react with different organolithium compounds and afforded the corresponding aminophosphane-borane complexes 4a–c and 9a-g. Acid methanolysis of those complexes led to the formation of the phosphinite-borane complexes 5a-c. This is a further example of the utilization of the industrial waste material (all-R)-2-azabicyclo-[3.3.0]octane-3-carboxylic acid. The catalytic efficiency of the chiral 1,3,2-oxazaphospholidine-borane complexes 3a, 3b, and 8c was examined in the enantioselective borane reduction of some ketones." @default.
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- W2950334589 date "1995-12-01" @default.
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- W2950334589 title "Utilization of industrial waste materials, 5. Synthesis of new, chiral 1,3,2-oxazaphospholidine-borane complexes and attempts to apply them in the stereoselective synthesis" @default.
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- W2950334589 doi "https://doi.org/10.1002/jlac.1995199512298" @default.
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