FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2950339110> ?p ?o ?g. }

• W2950339110 endingPage "153" @default.
• W2950339110 startingPage "146" @default.
• W2950339110 abstract "The [3 + 2] cycloaddition reactions of a series of ynoate esters with a ruthenium azido complex [Ru]−N3 (1, [Ru] = (η5-C5H5)(dppe)Ru, dppe = Ph2PCH2CH2PPh2) were investigated. The reaction products, metal-bound heterocyclic complexes such as the triazolato complexes [Ru]N3C2(CO2Et)2 (2), [Ru]N3C2(CO2Et)(CF3) (3), [Ru]N3C2(CO2Me)(Ph) (4) and [Ru]N3C2(CO2Et)(CH3) (5) were produced from diethyl acetylene dicarboxylate, ethyl 4,4,4-trifluoro-2-butynoate, methyl phenylpropiolate and ethyl 2-butynoate, respectively. The complexes were all structurally characterized as being N(2)-bound. The alkylation of 2 with organic halides resulted in the cleavage of the Ru−N bond and the formation of a series of 1-alkylated-4,5-bis(ethoxycarbonyl)-1,2,3-triazoles N3(CH2R)C2(CO2Et)2 (6a, R = H; 6b, R = C6F5; 6c, R = Ph; 6d, R = 4-CH2Br-C6H4; 6e, R = 4-CN-C6H4). The high regioselective alkylation of 4 with organic halides gave a 1-alkylated-4-phenyl-5-methoxycarbonyl-1,2,3-triazoles N3(CH2C6F5)C2(Ph)(CO2Me) (N3-7a). The structures of complexes 2, 3, 4, 5 and N3-7a were confirmed by single-crystal X-ray diffraction analysis." @default.
• W2950339110 created "2019-06-27" @default.
• W2950339110 creator A5049044702 @default.
• W2950339110 creator A5057574653 @default.
• W2950339110 date "2019-09-01" @default.
• W2950339110 modified "2023-10-02" @default.
• W2950339110 title "Synthesis of 1,4,5-trisubstituted triazoles by [3+2] cycloaddition of a ruthenium azido complex with ynoate esters" @default.
• W2950339110 cites W1748459267 @default.
• W2950339110 cites W1895879856 @default.
• W2950339110 cites W1969198686 @default.
• W2950339110 cites W1969300411 @default.
• W2950339110 cites W1977851521 @default.
• W2950339110 cites W1980916630 @default.
• W2950339110 cites W1982998720 @default.
• W2950339110 cites W1984864396 @default.
• W2950339110 cites W1986586468 @default.
• W2950339110 cites W2006369820 @default.
• W2950339110 cites W2007765039 @default.
• W2950339110 cites W2009941018 @default.
• W2950339110 cites W2011852598 @default.
• W2950339110 cites W2015301923 @default.
• W2950339110 cites W2016049050 @default.
• W2950339110 cites W2017082502 @default.
• W2950339110 cites W2021320094 @default.
• W2950339110 cites W2023557482 @default.
• W2950339110 cites W2026886823 @default.
• W2950339110 cites W2035317702 @default.
• W2950339110 cites W2039148075 @default.
• W2950339110 cites W2041326852 @default.
• W2950339110 cites W2041380845 @default.
• W2950339110 cites W2044353456 @default.
• W2950339110 cites W2065304353 @default.
• W2950339110 cites W2067112439 @default.
• W2950339110 cites W2069805392 @default.
• W2950339110 cites W2071772915 @default.
• W2950339110 cites W2072273100 @default.
• W2950339110 cites W2074949244 @default.
• W2950339110 cites W2076102240 @default.
• W2950339110 cites W2079152190 @default.
• W2950339110 cites W2084944709 @default.
• W2950339110 cites W2090712502 @default.
• W2950339110 cites W2092005238 @default.
• W2950339110 cites W2125141817 @default.
• W2950339110 cites W2158307905 @default.
• W2950339110 cites W2158397444 @default.
• W2950339110 cites W2162586071 @default.
• W2950339110 cites W2173882888 @default.
• W2950339110 cites W2315954308 @default.
• W2950339110 cites W2325938344 @default.
• W2950339110 cites W2472409727 @default.
• W2950339110 cites W2555967158 @default.
• W2950339110 cites W2560772808 @default.
• W2950339110 cites W2577017727 @default.
• W2950339110 cites W2600023060 @default.
• W2950339110 cites W2649942267 @default.
• W2950339110 cites W2753670749 @default.
• W2950339110 cites W2755469214 @default.
• W2950339110 cites W2790199368 @default.
• W2950339110 cites W2803534137 @default.
• W2950339110 cites W2910929187 @default.
• W2950339110 cites W2949622727 @default.
• W2950339110 cites W2950935744 @default.
• W2950339110 cites W2951876135 @default.
• W2950339110 cites W3005417761 @default.
• W2950339110 cites W3136593106 @default.
• W2950339110 cites W4232090531 @default.
• W2950339110 cites W4256503849 @default.
• W2950339110 cites W4256634851 @default.
• W2950339110 cites W57253423 @default.
• W2950339110 doi "https://doi.org/10.1016/j.jorganchem.2019.06.013" @default.
• W2950339110 hasPublicationYear "2019" @default.
• W2950339110 type Work @default.
• W2950339110 sameAs 2950339110 @default.
• W2950339110 citedByCount "5" @default.
• W2950339110 countsByYear W29503391102021 @default.
• W2950339110 countsByYear W29503391102022 @default.
• W2950339110 countsByYear W29503391102023 @default.
• W2950339110 crossrefType "journal-article" @default.
• W2950339110 hasAuthorship W2950339110A5049044702 @default.
• W2950339110 hasAuthorship W2950339110A5057574653 @default.
• W2950339110 hasConcept C127413603 @default.
• W2950339110 hasConcept C155647269 @default.
• W2950339110 hasConcept C161790260 @default.
• W2950339110 hasConcept C164361826 @default.
• W2950339110 hasConcept C171560689 @default.
• W2950339110 hasConcept C175156509 @default.
• W2950339110 hasConcept C178790620 @default.
• W2950339110 hasConcept C185592680 @default.
• W2950339110 hasConcept C187320778 @default.
• W2950339110 hasConcept C2777517455 @default.
• W2950339110 hasConcept C2779664164 @default.
• W2950339110 hasConcept C43369102 @default.
• W2950339110 hasConcept C555196967 @default.
• W2950339110 hasConcept C59759590 @default.
• W2950339110 hasConcept C71240020 @default.
• W2950339110 hasConceptScore W2950339110C127413603 @default.
• W2950339110 hasConceptScore W2950339110C155647269 @default.
• W2950339110 hasConceptScore W2950339110C161790260 @default.

• next