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- W2950342244 abstract "The polytypic structures formed in bulk Zr(Fe1 − xCrx)2 alloys (x = 0 to 1) in the as-cast and heattreated conditions (30 min at 850 or 900 °C) were determined by electron diffraction techniques. ZrCr2 was the only bulk alloy to exhibit a range of polytypic structures. The hexagonal polytypes 2H, 4H, 8H and 12H were present in as-cast ZrCr2. Upon heat treatment at 850 or 900 °C the hexagonal polytypes were replaced with the cubic polytype 3R and 3R-twinned. The cubic polytype 3R was the only structure formed in as-cast or heat-treated ZrFe2. The hexagonal polytype 2H was the only structure formed in Zr(Fe1 − xCrx)2 alloys (x = 0.25, 0.45 and 0.75) in all metallurgical conditions. This behaviour is compared with that of Zr(Fe1 − xCrx)2 (x ≠ 1) precipitates in zirconium-rich alloys where a variety of polytypes are observed. The presence of the polytype structures in the precipitates is attributed to the lattice misfit and associated distortional stresses present between the precipitates and the α-Zr matrix in the Zr-rich alloys. No such stresses would be present in the bulk alloys." @default.
- W2950342244 created "2019-06-27" @default.
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- W2950342244 date "1991-06-01" @default.
- W2950342244 modified "2023-10-09" @default.
- W2950342244 title "Polytypic structures in close-packed Zr(FeCr)2 Laves phases" @default.
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- W2950342244 doi "https://doi.org/10.1016/0022-5088(91)90047-8" @default.
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