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- W2950343061 abstract "The synthesis of small rings by functionalization of C(sp(3) )-H bonds remains a great challenge. We report for the first time a copper-catalyzed [1+1+1] cyclotrimerization of acetophenone derivatives under mild reaction conditions. The reaction has a broad scope for the stereoselective synthesis of cyclopropanes by trimerization of acetophenone. The developed transformation is based on an extraordinary copper-catalyzed cascade process that allows saturated carbocycles to be obtained for the first time by cyclotrimerization through functionalization of C(sp(3) )-H bonds. The cascade of sixfold C(sp(3) )-H bond functionalization allows the synthesis of cyclopropanes in a highly stereoselective approach." @default.
- W2950343061 created "2019-06-27" @default.
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- W2950343061 date "2016-07-01" @default.
- W2950343061 modified "2023-09-27" @default.
- W2950343061 title "ChemInform Abstract: [1 + 1 + 1] Cyclotrimerization for the Synthesis of Cyclopropanes." @default.
- W2950343061 cites W2307978780 @default.
- W2950343061 doi "https://doi.org/10.1002/chin.201630077" @default.
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